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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 15, Number 3
JKCSEZ 15(3)
June 20, 1971 

Synthesis of Cyclitol Derivatives (Ⅲ). Electrolytic Oxidation of myo-Inositol

Cyclitol 유도체 합성에 관한 연구 (제3보)-myo-Inositol의 전해 산화
Joo Hwan Sohn, Chong Woo Nam, Yu Ok Kim

손주환, 남종우, 김유옥
To obtain the various kinds of inosose stereomers, the process of electrochemical oxidation is more effective than chemical oxidation of myo-inositol. So that myo-inositol aqueous solution was electrolyzed by platinum and lead peroxide anode to confirming the occurrence of electrochemical oxidation. The result is that myo-inosose-2 is producing with high yield comparatively by electrolytic oxidation of myo-inositol. Also we studied about the relation between the electrolytic current efficiency and electrolytic temperature and anodic current density. The current efficiency is rising with lowering of electrolytic temperature identically in both anode such as platinum and lead peroxide and also rising with increasing of anodic current density in platinum anode, but inversely in lead peroxide.
127 - 132
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