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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 15, Number 2
JKCSEZ 15(2)
April 20, 1971 

 
Title
A Study on the Steam-Hydrocarbon Reforming Catalysts

탄화수소의 수증기개질 촉매에 관한 연구
Author
Lee Mook Kwon, Tae Soon Kim

권이묵, 김태순
Keywords
Abstract
In this study, several nickel catalysts for the steam-hydrocarbon reforming process were prepared from various nickel salt, magnesium oxide, alumina and kaolinite. The activity and strength of the catalysts were investigated. 1. The proper composition of the calcined catalysts are: NiO (5-15%)-MgO(10-20%)-Al2O3(10-40%)-Kaolinite(50-80%). 2. The admixed or cosedimented ingredients of the catalysts was pelletized and calcinated at 1000 or 1150℃. Calcination at 1150℃ for an hour was optimum. 3. The water to oil ratio (W/O) for reforming of hexane should be above 7 mole/mole. As the W/O increases, more carbon dioxide and hydrogen, but less carbon monoxide was produced. Also carbon deposition become lessen at higher W/O. 4. Maximum conversion had attained at about 850℃. As the reaction temperature increases, more carbon monoxide and hydrogen, but less carbon dioxide and lower hydrocarbon was produced. 5. The percent conversion at 850℃ was about 80%, using a catalyst which the nickel oxide content are 5%.
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