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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 14, Number 3
JKCSEZ 14(3)
June 20, 1970 

Effect of Additives on Gamma Radiolysis of Methanol
Sang Up Choi
Effect of added 1-hexene on the yield of hydrogen produced from Co-60 gamma radiolysis of methanol was investigated at room temperature. The results indicated that the yield of hydrogen decreased rapidly with increasing 1-hexene concentrations. Effect of added methyl borate on the radiolysis of methanol was also studied in the presence of oxygen. The results revealed that methyl borate acted as a less effective scavenger than oxygen towards the precursors of the radiolysis products. Experimental data previously obtained on the systems with oxygen added were treated more quantitatively to re-examine mechanism of the radiolysis of methanol in detail.
237 - 242
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