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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 13, Number 4
JKCSEZ 13(4)
August 20, 1969 

Study on the Coordination Polymers of Metal (Ⅱ) Ions with 2,5-Diamine 1,4-Dihydroxybenzene

2,5-Diamine 1,4-Dihydroxybenzene과 금속 (Ⅱ) 이온이 만드는 Coordination Polymer에 관하여
Joon Suk Oh, Kyun Ok Cho

A series of metal ion-2, 5-diamine 1, 4-dihydroxybenzene polymers containing copper(Ⅱ), nickel(Ⅱ) or cobalt (Ⅱ) have been prepared. The structure was postulated on the basis of elementary analysis of polymers. It was found that copper polymer is most likely the coordination polymers by X-ray powder pattern studies. The thermal stability of the polymers was also studied by a simple method, utilizing a thermogravimetric balance. The order of thermal stabilities is Cu(Ⅱ) > Ni(Ⅱ) > Co(Ⅱ). The polymers start to decompose at a relatively low temperature.
309 - 312
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