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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 13, Number 4
JKCSEZ 13(4)
August 20, 1969 

Extrathermodynamic Relationships for the Nucleophilic Addition Reaction of Mercaptan to a Carbon Double Bond

탄소이중결합에 대한 Mercaptan의 친핵성 첨가 반응의 Extrathermodynamic Relationship에 관한 연구
Ok-Hyun Park, Tae-Sup Uhm

박옥현, 엄태섭
The activation parameters for the nucleophilic addition reactions of n-propyl-, n-butyl-, n-amyl-and n-hexyl-mercaptan to 3, 4-methylene-dioxy-β-nitrostyrene were determined at pH 5.8 and pH 2.0, and also the isokinetic temperature of the reactions at pH 5.8 was obtained numerically 262。K, and at pH 2.0, 17.1 K. From the values obtained above, the fact that the mercaptan having the longer carbon chain has the greater nucleophilicity of it in the addition reactions has been discussed by the extrathermodynamic analysis of ΔH≠and ΔS≠.
297 - 302
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