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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 13, Number 3
JKCSEZ 13(3)
June 20, 1969 

 
Title
Ring-Opening Reaction of 2,2-gem-Diphenylaziridine

2,2-gem-Diphenylaziridine의 개환반응
Author
Chi Sun Hahn, Ha Il Nam-Goong, Yong Ik Kang

한치선, 남궁하일, 강용익
Keywords
Abstract
2,2-gem-dephenylaziridine의 초산에 의한 개환반응에서 반응생성물은1,1-diphenyl-2-amino-ethyl acetate 임을 알았다. 또한 이 개환반응은 aziridine환 안에 있는 질소원자와 tertiary탄소원자사이의 결합이 절단되어 중간체로서 carbonium이온이 형성되는 과정을 거쳐서 진행됨을 알았다.

A study of the ring-opening reaction of 2,2-gem-diphenylaziridine by treating with acetic acid has been undertaken. The structure of the ring-opened product was confirmed as 1,1-diphenyl-2-aminoethyl acetate. It is most likely that the reaction proceeds through the cleavage of a bond between nitrogen and tertiary carbon atoms in the aziridine ring, followed by the formation of a carbonium ion intermediate.

Page
229 - 232
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