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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 12, Number 2
JKCSEZ 12(2)
April 20, 1968 

 
Title
Derivation of Some Activation Parameters

새로운 활성화 파라메터의 유도
Author
Ikchoon Lee

이익춘
Keywords
Abstract
Compressibility and expansibility of activation, ΔK≠ and ΔE≠, are defined with the use of general principles that an activation parameter is the difference in partial molar quantities of the parameter for the transition and initial state. Two related parameters, (∂ΔH≠/∂P)T and ΔW≠(=PΔV≠), are also derived. Simpler interpretation of the existing kinetic data are possible with these activation parameters, while other derivations lead to complicated expressions of no practical significance.
Page
61 - 64
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