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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 11, Number 4
JKCSEZ 11(4)
August 20, 1967 

 
Title
Transient State Theory of Significant Liquid Structure Applied to A Binary Mixture of Benzene and Carbon Tetrachloride

이성분 액체 혼합물 (C6H6-CCl4)의 통계열역학적 연구
Author
Dong Sik Choi, Woon Sun Ahn, Kak Choong Kim, Seihun Chang

최동식, 안운선, 김각중, 장세헌
Keywords
Abstract
액체 구조에 관한 천이상태 이론을 벤젠과 사염화탄소의 이성분 액체 혼합물에 적용시켰다. 각 성분의 상태합으로부터 액체 혼합물계의 상태합을 구하고, 이것으로부터 전체압, 부분압, 몰부파, 혼합엔트로피 및 압축율 등의 열역학적 성질을 여러 온도에서 계산하였다. 계산 결과는 문헌에서 얻은 실험값과 근사적으로 일치함을 발견하였다.

The Transient State Theory of Significant Liquid Structure is applied to a binary liquid solution of benzene and carbon tetrachloride, which gives slightly positive deviation from Raoults law. The partition function for the solution is derived according to the proposed theory. The various thermodynamic properties such as total and partial vapor pressures, molar volumes, entropies of mixing, and compressibilities are calculated at three different temperatures, 298.15˚K, 313.15˚K and 343.1515。K. The calculated values agree satisfactorily with experimental data.

Page
143 - 149
Full Text
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