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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 10, Number 4
JKCSEZ 10(4)
August 20, 1966 

 
Title
Determination of Nucleophilic Addition Constant to β-Nitrostyrene (Ⅰ)

β-Nitrostyrene에 대한 Nucleophilic Addition Constant의 측정 (Ⅰ)
Author
Tae-Rin Kim, Young-Sang Choi

김태린, 최영상
Keywords
Abstract
여러가지 nucleophile을 써서 3,4-methylene-dioxy-β-nitrostyrene에 대한 nucleophilic addition constant를 측정하여 이미 알려진 nucleophilic substitution constant와 비교해 보았더니, 이 둘 사이에는 비례관계가 성립되지 않으리라 생각된다. 이것을 정량적으로 취급하려면 앞으로 많은 nucleophile에 대해서 더욱 정확한 실험치를 얻을 수 있어야 하겠다.

The nucleophilic addition constants 3,4-methylenedioxy-β-nitrostyrene were determined for various nucleophiles. Considerably more data would be desirable, but it appears at present that there is no proportionality between the nucleophilic addition and substitution constant.

Page
158 - 160
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