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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 10, Number 4
JKCSEZ 10(4)
August 20, 1966 

Determination of Nucleophilic Addition Constant to β-Nitrostyrene (Ⅰ)

β-Nitrostyrene에 대한 Nucleophilic Addition Constant의 측정 (Ⅰ)
Tae-Rin Kim, Young-Sang Choi

김태린, 최영상
여러가지 nucleophile을 써서 3,4-methylene-dioxy-β-nitrostyrene에 대한 nucleophilic addition constant를 측정하여 이미 알려진 nucleophilic substitution constant와 비교해 보았더니, 이 둘 사이에는 비례관계가 성립되지 않으리라 생각된다. 이것을 정량적으로 취급하려면 앞으로 많은 nucleophile에 대해서 더욱 정확한 실험치를 얻을 수 있어야 하겠다.

The nucleophilic addition constants 3,4-methylenedioxy-β-nitrostyrene were determined for various nucleophiles. Considerably more data would be desirable, but it appears at present that there is no proportionality between the nucleophilic addition and substitution constant.

158 - 160
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