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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 10, Number 3
JKCSEZ 10(3)
June 20, 1966 

Transient State Theory of Significant Liquid Structure applied to Binary Mixture, Benzene-Cyclohexane

이성분 액체 혼합물의 통계열역학적 연구
Woon Sun Ahn

벤젠-시클로핵산 이성분 용액에다 Transient State Theory of Significant Liquid Structure를 확장 적용시켰다. 상태함을 구하고 이것으로부터 계의 전체압, 부분압, 몰부피 그리고 과량의 엔트로피와 같은 열역학적 양을 303.15˚, 313.15˚및 343.15˚K에서 계산하였다. 이와 같이 구한 계산치들은 실측치와 대단히 잘 맞았다.

The Transient State Theory of Significant Liquid Structure has been successfully extended to binary mixture, benzene-cyclohexane system, which gives positive deviation from Raoult's law. The partition function has been derived, and from it various thermodynamic properties, such as total and partial vapor pressures, molar volumes, and excess entropies have been calculated at the temperatures 303.15°, 313.15°and 343.15。K. The calculated values agree satisfactorily with the experimental data.

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