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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 9, Number 3
JKCSEZ 9(3)
June 20, 1965 

 
Title
Halogen Exchange Reactions of Benzyl Halides (Part 1) Kinetics of Reactions of Chloride and Bromide Ions with Benzyl Chloride and Bromide

벤질할라이드의 할로겐교환반응 (제1보) 염화 및 취화 벤질과 염소 및 취소이온과의 반응속도
Author
Kyung Hoon Jung, Yeon Hun, Ikchoon Lee

정경훈, 허연, 이익춘
Keywords
Abstract
Benzyl chloride 및 bromide와 chloride 및 bromide ion 간의 반응을 90% ethanol 용액에서반응속도론적으로 연구하였다. 반 정량적인 결과의 해석은 bond-formation 이 bond-breaking보다 더 중요하고 또 결합형성 과정에서는 형성으로 얻은 energy보다는 nucleophile의 electron affinity의 증가로 인한 차이가 더 중요함을 보여주고 있다.

Kinetics of reactions of chloride and bromide ions with benzyl chloride and bromide have been investigated in 90% ethanol solution. Semi-quantitative analysis of the results shows that the bond-formation is more important than the bond-breaking and furthermore in bond-formation the energy gain due to bond-formation is less than the increase in electron affinity of the nucleophile.

Page
148 - 151
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