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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 9, Number 2
JKCSEZ 9(2)
April 20, 1965 

 
Title
Halogen Containing Heterocyclic Compounds (Part 1) Chlorination of Furfurylacetate

함할로겐 이원소환화합물에 관한 연구 (제1보) Furfurylacetate 의 Chlorination 반응
Author
You Sun Kim, Jin Sung Chung

김유선, 정진성
Keywords
Abstract
초산풀퍼릴을 합성하여 여러가지 반응조건하에서 염소화시킨 결과 저온반응에서 안정한 trans 사염화물(평균수율 25∼30%)을 생성하였고, 삼염화물의 생성은 거의 없었다. 고온반응에서는 반응생성물의 분해가 심하였다. 염소화반응조건, 생성물의 분리방식 및 안정도, 입체화학구조에 대하여 각각 논급하였다.

Furfurylacetate was prepared and was chlorinated under various reaction conditions. At the low reaction temperature the chlorination product was composed of the stable trans-tetrachloride (yield, 25∼30%), decomposition product (low chlorine content), and unstable cis-tetrachloride. There were no appreciable quantity of the trichloride. At the high reaction temperature the chlorination products were exclusively decomposed. The reaction conditions, separation scheme, and the configurataion of the product were discussed.

Page
81 - 87
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