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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 8, Number 2
JKCSEZ 8(2)
April 20, 1964 

 
Title
The Significant Structures of Liquid Fluorine

액체 풀루오르의 구조에 관하여
Author
Mu Shik Jhon, Seihun Chang

전무식, 장세헌
Keywords
Abstract
H. Eyring등에 의하여 제안된 액체구조에 관한 이론에 따라서 액체의 partition function을 정하였다. parameter Es, Vs, Θ, a는 앞서 저자들에 의해 제안된 방법에 의하여 정하였고, 이렇게 정해진 partition function을 써서 액체의 몰부피, 증기압, 한계점. 증발엔트로피 및 표면장력등을 계산한 결과 실측자와 잘 맞는 값을 얻었다.

The partition function of liquid fluorine were developed by applying the theory of significant structures in liquids. The molar volume, vapor pressure, entropy of vaporization and surface tension of the liquid were calculated over a wide temperature range. The critical properties for the liquid were also calculated. The results show good agreement with experimental observations.

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65 - 67
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