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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 57, Number 5
JKCSEZ 57(5)
October 20, 2013 

The Effect of Nonrandom Distribution of Molecules on the Equation of State for Gases

분자의 논랜덤 분포가 기체의 상태방정식에 미치는 영향
Hae Young Jung*

Equation of state, Nonrandom distribution, Nonrandom mixing
Using the free volume of van der Waals equation, Carnahan-Starling equation for hard spheres, Wilson equation for nonrandom mixing of solution, NRTL equation and our equation, several new equations of states for pure gases are derived. Using these equations, compressibility factors for pure gases are calculated and compared with Nelson-Obert generalized compressibility factor charts. The equation of states using the concept of molecular nonrandom distribution gave better results than those of molecular random distribution. This shows that the molecular nonrandom distribution makes considerable effect on the equation of states.
540 - 546
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