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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 56, Number 6
JKCSEZ 56(6)
December 20, 2012 

Micellar Catalysis on 1,10-Phenanthroline Promoted Chromic Acid Oxidation of Ethane-1,2-diol in Aqueous Media at Room Temperature
Sumanta K Ghosh, Rumpa Saha*, Aniruddha Ghosh, Ankita Basu, Kakali Mukherjee, Indrajit Saha, Bidyut Saha*
1,10-Phenanthroline, Ethane 1,2-diol, SDS, CPC, TX-100
Under pseudo-first order conditions, the monomeric species of Cr(VI) was found to be kinetically active in the absence of phenanthroline (phen) whereas in the phen-promoted path, the Cr(VI)-phen complex undergoes a nucleophilic attack by etane-1,2-diol to form a ternary complex which subsequently experience a redox decomposition leading to hydroxy ethanal and Cr(III)-phen complex. The effect of the cationic surfactant (CPC), anionic surfactant (SDS) and neutral surfactant (TX-100) on the unpromoted and phen-promoted path have been studied. Micellar effects have been explained by considering the preferential partitioning of reactants between the micellar and aqueous phase. Combination of TX-100 and phenanthroline will be the ideal for chromic acid oxidation of ethane-1,2-diol in aqueous media
720 - 724
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