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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 55, Number 4
JKCSEZ 55(4)
August 20, 2011 

Preparation of Supported CTAB/MCM-41 and CTAB-Nafion/MCM-41 Mesoporous Molecular Sieve and Their Use in the Brominating Reaction

담지된 CTAB/MCM-41 and CTAB-Nafion/MCM-41 메조다공성 분자체의 제조 및 브롬화 반응에 사용
Guoqin Hu*, Hua Li, Juan Liu, Jiang Zhu

Guoqin Hu*, Hua Li, Juan Liu, Jiang Zhu
메조다공성 분자체 MCM-41, 상전달 촉매, 산성 촉매, 담지 , Mesoporous melecular sieve MCM-41, Phase-transfer catalyst, Acidity catalyst, Supported, Brominating reaction
CTAB 혹은 CTAB-나피온 촉매를 속빈 실리콘 튜브형 MCM-41에 담지시켰다. 이들 촉매들을 XRD, SEM, BET 등으로 분석하였다. 이들을 1,7-heptanediol 의 브롬화 반응 촉매로 사용하였고 다른 촉매들과 비교하였다. 이들 촉매들은 CTAB 보다 효과가 좋았으며 CTAB-Nafion/MCM-41 이 성능이 가장 우수하였다.

CTAB or CTAB-Nafion catalyst were successfully supported on siliceous hollow tubular MCM-41 which synthesized by hydrothermal method using CTAB as a single template or CTAB and Nafion-Na as mixed templates. The properties of two kinds of catalysts were characterized with XRD, SEM and adsorption and desorption isotherms of nitrogen and pore diameter distribution, respectively. Then they were applied to catalyze brominating reaction of 1,7-heptanediol, moreover the rate of brominating reaction with different catalysts was compared. The results showed that catalytic activities of CTAB/ MCM-41 and CTAB-Nafion/MCM-41 are better than CTAB, and that of CTAB-Nafion/MCM-41 is the best because of its phase-transfer and strong acidity function. The two kinds of catalysts can be separated from the reactive products and recycled.

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