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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 54, Number 1
JKCSEZ 54(1)
February 20, 2010 

 
Title
Selective Reduction of Nitro Compounds Using CeY Zeolite Under Microwaves

마이크로웨이브와 CeY Zeolite를 이용한 니트로화합물의 선택적인 환원반응#
Author
Kapil Arya*, Anshu Dandia

Kapil Arya*, Anshu Dandia
Keywords
CeY zeolite, 마이크로웨이브, 환원, 니트로 화합물 , CeY zeolite, Monomode reactor, Microwaves, Reduction, Nitro compounds
Abstract
포화 그리고 방향족 니트로화합물은 monomode reactor로 CeY zeolite와 formic acid를 사용하여 반응시키면 아민 치환체를 좋은 수율로 선택적으로 환원된다. 이 반응은 몇개의 민감한 작용기를 가진 화합물에 적합하다. 회수한 촉매를 20회 이상 사용 후에도 촉매의 활성을 계속 유지하였다.

Aliphatic and aromatic nitro compounds were selectively reduced to their corresponding amino derivatives in good yields using formic acid and CeY zeolite under monomode reactor. This system is found to be compatible with several sensitive functionalities. Beside the recycling result showed it had a long catalyst lifetime and could maintain activity even after being used for 20 cycles.

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