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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 51, Number 3
JKCSEZ 51(3)
June 20, 2007 

 
Title
Structural Characterization of the Eight-Coordinated Dodecahedral Y(tpb)3(H2O)2

8배위 12면체 Y(tpb)3(H2O)2 착물의 합성과 구조
Author
Chongnam Yu, Seong-Joo Kang*

유종남, 강성주*
Keywords
이트륨, 12면체 구조, tpb 리간드 , Yttrium, dodecahedron, tpb β-diketonate ligand
Abstract
8배위 이트륨(III) 화합물 Y(tpb)3(H2O)2을 합성하였고 X-선 회절법으로 구조를 규명하였다. 이 화합물은 12 면체의 구조를 가지며, 두 면(Y-O2-O1-O5-O6 and Y-O4-O3-O8-O7)사이의 각은 89.59o이다. 또한, O1-O5과 O3-O8 의 거리는 2.965 and 2.995 A이며 O2-O6과 and O4-O7의 거리는 4.256 and 4.403 A이다.

The eight coordinated yttrium(III) complex Y(tpb)3(H2O)2 (Htpb=4,4,4-Trifluoro-1-phenyl-1,3-butanedione) has been synthesized and structurally characterized by X-ray diffraction method. The coordination polyhedron of Y(tpb)3(H2O)2 has a dodecahedron. The angle between two trapezia, Y-O2-O1-O5-O6 and Y-O4-O3-O8-O7, is 89.59°. The O1-O5 and O3-O8 distances are 2.965 and 2.995 A whereas the O2-O6 and O4-O7 distances are 4.256 and 4.403 A.

Page
240 - 243
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