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ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 48, Number 4
JKCSEZ 48(4)
August 20, 2004 |
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Title |
Synthesis of New BF2-Chelate Compounds
새로운 BF2-Chelate 화합물들의 합성
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Author |
Jung-Hwan Kim, Yeung-Eun Kim
김정환, 김영은
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Keywords |
H-킬레이트, BF2-킬레이트, 2-(1-BF2)Pyridyl-4-(6-chloro)pyrimidylideneacetonitrile 유도체들
, H-Chelate, BF2-Chelate, 2-(1-BF2)Pyridyl-4-(6-chloro)pyrimidylideneacetonitrile Derivatives
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Abstract |
BF2-chelate 형태의 4-pyrimidylideneacetonitrile 유도체들은 4-pyrimidylideneacetonitrile 유도체들의 H-chelate 화합물들과 boron trifluoride diethyl etherate를 반응시켜 얻을 수 있었다. 또 이들 H-chelate 화합물들은 2-cyanomethylpyridine 유도체들에 여러가지 친전자체들 즉 4,6-dichloropyrimidine, 4,6-dichloro-2-methylpyrimidine, 4,6-dichloro-2-heptadecylpyrimidine, 4,6-dichloro-2-phenylpyrimidine, 4,6-dichloro-5-phenylpyrimidine 그리고 4,6-dichloro-2,5-diphenylpyrimidine을 친전자성 치환반응시켜 만들었다. 화합물에 대한 구조는 분광학적인 방법으로 분석하였다.
4-pyrimidylideneacetonitrile derivatives containing BF2-chelate have been synthesized from H-chelates of 4-pyrimidylideneacetonitrile derivatives and boron trifluoride diethyl etherate. These H-chelates were prepared by the electrophilic substitution of 2-cyanomethylpyridine derivatives with electrophiles such as 4,6-dichloropyrimidine, 4,6-dichloro-2-methylpyrimidine, 4,6-dichloro-2-heptadecylpyrimidine, 4,6-dichloro-2-phenylpyrimidine, 4,6-dichloro-5-phenylpyrimidine and 4,6-dichloro-2,5-diphenylpyrimidine. Structures of the target molecules were identified by spectra methods.
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379 - 0 |
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