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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 47, Number 4
JKCSEZ 47(4)
August 20, 2003 

 
Title
Structure of Chloro bis(1,10-phenanthroline)Cobalt(II) Complex, [Co(phen)2(Cl)(H2O)]Clㆍ2H2O

Structure of Chloro bis(1,10-phenanthroline)Cobalt(II) Complex, [Co(phen)2(Cl)(H2O)]Clㆍ2H2O
Author
Pu Su Zhao, Lu De Lu, Fang Fang Jian

Pu Su Zhao, Lu De Lu, Fang Fang Jian
Keywords
코발트 착화합물, 1,10-Phenanthroline, 수소결합, 그물구조 , Cobalt Complexes, 1,10-Phenanthroline Ligands, Hydrogen Bonds, Network
Abstract
[Co(phen)2(Cl)(H2O)] Clㆍ2H2O(phen=1,10-phenanthroline)의 결정구조는 X-ray에 의하여 결정되었다. 그 결정은 a=9.662(2), b=11.445(1), c=13.037(2)Å α=64.02(1), β=86.364(9), γ=78.58(2)° 그리고 Z=2의 격자인자를 갖는 triclinic계와 space group이 P1의 구조로 결정화 되었다. 배위된 양이온은 두개의 Phen 리간드, 하나의 chloride이온과 하나의 H2O 리간드가 cis 배열로 킬레이크된 6배위 코발트 원자가 포함된다. 코발트에 배위된 chloride에 더해서, 결정구조를 이루는 하나의 chloride이온과 네개의 물분자가 있다. 고체상태에서, 제목의 화합물은 수소결합을 통하여 3차원 그물구조를 갖는다.

The crystal structure of [Co(phen)2(Cl)(H2O)] Clㆍ2H2O(phen=1,10-phenanthroline) has been determined by X-ray crystallography. It crystallizes in the triclinic system, space group P1, with lattice parameters a=9.662(2), b=11.445(1), c=13.037(2)Å α=64.02(1), β=86.364(9), γ=78.58(2)°, and Z=2. The coordinated cations contain a six-coordinated cobalt atom chelated by two phen ligands and one chloride anion and one water ligand in cis arrangement. In addition to the chloride coordinated to the cobalt, there are one chloride ion and four water molecules which complete the crystal structure. In the solid state, the title compound forms three dimensional network structure through hydrogen bonds, within which exists the strongest hydrogen bond (O(3)-O(4)=2.33Å). The intermolecular hydrogen bonds connect the [Co(phen)2(Cl)(H2O)]1+, H2O moieties and chloride ion.

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