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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 45, Number 6
JKCSEZ 45(6)
December 20, 2001 

Synthesis of New 2-Quinazolylacetonitrile Derivatives

새로운 2-Quinazolylacetonitrile 유도체들의 합성
Jung-Hwan Kim, Kyung-Su Min

김정환, 민경수
H-chelate형태의 2-Quinazolylacetonitrile유도체들은 2-cyanomethylquinazoline에 여러가지 친전자체들, 즉, 4-chloroquinazoline, 4-chloro-2-phenylquinazoline, 4,6-dichloropyrinidine, 4,6-dichloro-2-phenylpyrimidine, 4,6-dichloro-5-phenylpyrimidine, 2-chloroauinoxaline,1,3- dichloroisoquinoline, 2,6-dichloropyrazine, 2-chloropyrazine, 4,6-dichloro-2,5-diphenylpyrimidine 등을 반응시켜 얻을 수 있었다. 합성된 H-chelate화합물들은 polymethine계의 발색단 구조를 가지게 된다. 이들 화합물에 대한 구조는 분광학적인 방법으로 분석 확인 하였다.

2-Quinazolylacetonitrile derivatives containing H-chelate have been synthesized from 2-cyanomethylquinazoline using electrophiles such as 4-chloroquinazoline, 4-chloro-2-phenylquinazoline, 4,6-dichloropyrimidine, 4,6-dichloro-2-phenylpyrimidine, 4,6-dichloro-5-phenylpyrimidine, 2-chloroquinoxaline, 1,3-dichloroisoquinoline, 2,6-dichloropyrazine, 2-chloropyrazine and 4,6-dichloro-2,5-diphenylpyrimidine. These H-chelates may serve as a polymethine chromophore system. Structures of the target molecules were identified by spectral methods.K010606

532 - 537
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