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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 20, Number 7
BKCSDE 20(7)
July 20, 1999 

Thermal and Photoinduced Silylalylation Reactions of Organic halides with 3-Stannyl-2-(silylmethyl)propene
Kyung-Tae Kang, Seong Sim Hwang, Woo Young Kwak, Ung Chan Yoon
Thermal and photoinduced silylallylation reactions of organic halides with 3-stannyl-2-(silylmethyl)propene are explored. Silylallylations occur in moderate to high yields, producing various functionalized allylsilane products in which halide carbon is bonded to the terminal alkenic carbon of allylsilane with the removal of tributyltin group. The reactions, which tolerate functional groups such as carbonyl, ester, nitrile, acetal, and ketal, hold synthetic potential for the construction of functionalized allylsilanes.
801 - 804
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