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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 20, Number 1
BKCSDE 20(1)
January 20, 1999 

Ni/γ-Al2O3 Catalyst Prepared by Liquid Phase Oxidation for Carbon Dioxide Reforming of Methane
Kyoung Soo Jung, Byoung-Youl Coh, Ho-In Lee
Carbon dioxide reforming of methane on Ni/γ-Al2O3 catalyst was studied. A new 10 wt% Ni/γ-Al2O3 catalyst prepared by the liquid phase oxidation method (L10O) exhibited much higher activity as well as resistances to both sintering and coke formation during the reaction than the catalyst prepared by the conventional impregnation method (D10). The electrically strong attractive interaction between nickel and support during the liquid phase oxidation process and the resultant high nickel dispersion made the L10 have superior activity and stability to the D10. To elucidate the results, the experiments with nickel catalysts on the other supports as well as 7-AI203 were performed. The effect of sodium as a promoter was also studied.
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