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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 19, Number 1
BKCSDE 19(1)
January 20, 1998

Title	Synthesis of Novel 9-Fluoroanthracycline Derivatives
Author	Young S. Rho*, Siho Park, Sun Y. Kim, Inho Cho, Chulhyun Lee, Heun S. Kang, Chaejoon Cheong
Keywords
Abstract	Synthesis of novel 9-fluoroanthracyclines carrying L-fucose as a sugar component is described. Compound 3 containing a fluorine at the C-9 position was synthesized from an epoxide 2 and HF/Pyr (7 : 3). Bromination and hydrolysis of compound 3 resulted in synthesis of an aglycone, 9-fluoroanthracyclinone 6. The α-(1b) and β -anomers (1a) of the final product were obtained in high yields by a coupling reaction with the L-fucose.
Page	74 - 78
Full Text	PDF

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