Current time in Korea 18:17 Jan 21 (Thu) Year 2021 KCS KCS Publications
KCS Publications
My Journal  Log In  Register
HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 18, Number 5
BKCSDE 18(5)
May 20, 1997 

Electrochemical Behaviour of merdional tris(2-pyridinethiolato)Cobalt(Ⅲ) in Dimethylformamide Solution
Jung-Kyoon Chon, Hee K. Chae, Yongtae Kim, Yongbok Go, Ok-Sang Jung
Electrochemical behavior of mer-tris(2-pyridinethiolato)cobalt(Ⅲ) in dimethylformamide was studied on a platinum electrode by means of cyclic voltammetry, chronoamperometry, and chronocoulometry. It was found that the neutral complex molecule was electroactive between the potential region of 1.0 and - 1.2 V vs. a nonaqueous Ag/Ag+ electrode. The Co(Ⅲ) complex was reversibly reduced to Co(Ⅱ) species by one-electron transfer at about - 1.1 V, followed by an irreversible dissociation reaction. However, the oxidation process at around 0.8 V, was responsible for an irreversible two-electron transfer that occurred at a ligand site.
496 - 500
Full Text