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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 17, Number 9
BKCSDE 17(9)
September 20, 1996 

Synthesis and Characterization of Copper(Ⅱ) Complex Containing 2,2'-dipyridylbenzamide
Donghwan Lee, Byungsoon Kim, Yunghee Oh*, Myung Soo Lah, Wonghil Chang
A new copper complex containing 2,2'-dipyridylbenzamide(dpba), Cu(dpba)(NO3)2(CH3CN), has been synthesized and characterized. The crystal structure has been determined. Crystal data: space group P212121, Z=8, a=13.911(3) Å, b=16.813(3) Å, c=18.932(3) Å, V=4427.9(1) Å3 and R=0.0674 for 1716 reflections. The copper environment is square pyramidal containing acetonitrile in axial site. Spectroscopic properties has been characterized in solution state. The redox property of the Cu(dpba)(NO3)2 complex is different from that of corresponding copper-dpa complex.
836 - 839
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