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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 16, Number 12
BKCSDE 16(12)
December 20, 1995 

 
Title
Regioselective Friedel-Crafts Reaction of Allyldichlorosilane with 3,4-Benzo-1,1-dichloro-1-silacyclopentene
Author
Young Tae Park,* Sang Ug Park, Ho Chang Kim
Keywords
Abstract
A 86:14 isomeric mixture of 3,4-[3'-(dichlorosilyl)isopropyl]benzo-1,1-dichlor o-1-silacyclopentene and 3,4-[2'-(dichlorosilyl)isopropyl]benzo-1,1-dichlor o-1-silacyclopentene was prepared by the regioselective Friedel-Crafts reaction of allyldichlorosilane with 3,4-benzo-1,1-dichloro-1-silacyclopentene catalyzed by Lewis acid AlCl3. The structure of the products was confirmed by methylation with methylmagnesium bromide and by methoxylation with trimethylorthoformate.
Page
1208 - 1212
Full Text
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