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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 16, Number 5
BKCSDE 16(5)
May 20, 1995 

 
Title
Catalytic Asymmetric Allylic Alkylation with A Novel P-S Bidentate Ligand
Author
Jahyo Kang*, Sung Hoon Yu, Joo In Kim, Hyung Geun Cho
Keywords
Abstract
Both enantiomers of (S)-(-)-2-(diphenylphosphino)-2'-mercapto-1,1'-bin aphthyl and their derivatives were obtained by synthesis from racemic 2,2'-dihydroxy-1,1'-binaphthyl and subsequent resolution. The utilities of these ligands were investigated briefly. And among these, S-methyl derivative 15 has proved to be an effective ligand for Pd-catalyzed allylic alkylation.
Page
439 - 443
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