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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 15, Number 11
BKCSDE 15(11)
November 20, 1994 

The LS→HS Transition of Cobalt(Ⅲ) in an Oxygen Lattice with the K2NiF4-Type Structure : Correlations with the Chemical Bonding Environment of the (CoO6) Octahedron Along the c-axis
Song-Ho Byeon, Gerard Demazeau*
In oxides characterized by the K2NiF4-type structure, the low-spin→high-spin transition of trivalent cobalt ion was studied in function of the nature of competing bonds in the perovskite-plane and along the c-axis. Using Slichter and Drickamer's model the calculated values of parameters characterizing such a transition are correlated with the covalency of competing bonds along the c-axis of the K2NiF4-structure and the local structural distortion of the (CoO6) octahedron.
949 - 953
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