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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 15, Number 7
BKCSDE 15(7)
July 20, 1994 

 
Title
Kinetic Studies on the Reaction of the Heterobimetallic Anion, (OC)5CrMn(CO)5-M+ (M+=Na+, PPN+α) with CH3I
Author
Yong Kwang Park*, In Sup Han, Jin Ho Kim, Choon Ja Lee, Youn Ok Baek, Gwan Ok Song
Keywords
Abstract
The reaction of the heterobimetallic anion, (OC)5CrMn(CO)5-M+ (M+=Na+, PPN+) with CH3I was proven to be overall 1st order with respect to [(OC)5CrMn(CO)5-] This reaction mechanism may be described in terms of the consecutive reaction pathway in which Cr(CO)5(THF) may be an important intermediate, leading to the corresponding products such as MeMn(CO)5 and ICr(CO)5-, accordingly. The counterion effect on this reaction was also elucidated.
Page
537 - 541
Full Text
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