Current time in Korea 15:26 Jul 22 (Mon) Year 2019 KCS KCS Publications
KCS Publications
My Journal Log In Register
HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 15, Number 6
BKCSDE 15(6)
June 20, 1994 

 
Title
Studies on Electrochemical properties of Lithium/Oxyhalide Cell : Electrocatalytic Effects on the Reduction of Thionyl Chloride
Author
Woo-Seong Kim, Yong-Kook Choi*, Ki-Hyung Chjo
Keywords
Abstract
Catalytic effects of various cobalt phenylporphyrin compounds on the reduction of thionyl chloride at glassy carbon electrode have been evaluated by determining kinetic parameters with cyclic voltammetric techniques. The concentration of catalysts and the electrode immersion time have been found to affect the catalyst performance strongly, leading to a conclusion that the compounds are first adsorbed at the electrode surface and act as catalysts. Significant improvements in cell performance have been noted in terms of both exchange rate constants of up to 3 times and current densities of up to 150% at glassy carbon electrode.
Page
456 - 460
Full Text
PDF