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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 15, Number 5
BKCSDE 15(5)
May 20, 1994

Title	Syntheses of Morindaparvin A and Its Derivatives
Author	Young S. Rho*, Si Ho Park, Sunglyeol Kim, Yeo Keun Yun, In Ho Cho, Heun-Soo Kang
Keywords
Abstract	A general route for convergent syntheses of morindaparvin derivatives with 1,2-methylene-dioxyanthraquinone pattern is described. The anion of 2-methoxycyclohexanone (3), generated with lithium cyclohexylisopropylamine at -78 ℃, was sulfenylated with phenyl phenylthiosulfonate followed by elimination to afford α,β -unsaturated carbonyl system 8. 6-Methoxy-2-cyclohexen-l-one (8) was condensed with the four phthalide sulfones derivatives 10a-d, to provide morindaparvin derivatives, 1a-d.
Page	360 - 364
Full Text	PDF

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