KCS Publications

HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 15, Number 5
BKCSDE 15(5)
May 20, 1994

Title	Substractively Normalized Interfacial Fourier Transform Infrared Spectroscopic Study of Cyanide Ions at Gold Electrode
Author	Dong Hee Son, Kwan Kim*
Keywords
Abstract	The adsorption of cyanide ion on the gold electrode has been investigated by the substractively normalized interfacial Fourier transform infrared spectroscopy (SNIFTIRS). The observations made by SNIFTIRS were consistent with those obtained by the polarization modulated Fourier transform infrared spectroscopy. According to the surface selection rule, cyanide ion appeared to adsorb on gold via either carbon or nitrogen lone pair electrons assuming a perpendicular orientation with respect to the metal surface. The possibility of presence of bridge-bound species seemed very infeasible. From the ab initio quantum mechanical calculation, adsorbate-to-metal bonding appeared to occur mainly via the 5σ donation from carbon to Au.
Page	357 - 360
Full Text	PDF

How to access to the WOL for The Bulletin of the Korean Chemical Society ?

The Bulletin of the Korean Chemical Society will be co-published with Wiley-VCH from 2015 towards. The online version of the Journal will thus be available on Wiley Online Library, Wiley(-VCH)'s global online platform.

KCS members can get a free online access to the Bulletin of the Korean Chemical Society in WOL.

Free Access to WOL