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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 15, Number 3
BKCSDE 15(3)
March 20, 1994 

Simultaneous Determination of Diffusion Coefficient and Concentration by Chronoamperometry at a Microdisk Electrode
Yongju Jung, Juhyoun Kwak*
Two unknown values among three electrochemical values, i.e. electrode area, diffusion coefficient, and concentration, are simultaneously obtained by nonlinear regression analysis of a single chronoamperometric faradaic current curve at a microdisk electrode. The approach is an analytical application of the semi-empirical equation presented by Shoup and Szabo for the chronoamperometric response at a disk electrode. To demonstrate the usefulness and accuracy of this approach, the chronoamperometric current at a platinum disk electrode of 50 μm radius in solutions of Ru(NH3)63+, ferrocene, Fe(CN)63-, and C60, were analyzed.
209 - 213
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