KCS Publications

HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 15, Number 1
BKCSDE 15(1)
January 20, 1994

Title	Revised Reversible and Totally Irreversible Zones for the Linear Sweep Voltammetry at a Planar Electrode
Author	Juhyoun Kwak*
Keywords
Abstract	Digital simulation program for one-dimensional geometric systems of electrochemical phenomena was developed. The accuracy of the digital simulation is discussed by comparing with the known solutions. Applying this program to the linear sweep voltammetry at a planar electrode for the electrode reaction, 0 + ne→R, the accurate current functions for the reversible and totally irreversible charge transfer systems were obtained. Comparing these current functions with the simulated voltammograms for various other values of α (0.1 to 1.0) and Λ (10-5 to 105), the revised zones that are different from those proposed by Matsuda and Ayabe for the reversible and totally irreversible systems are proposed. For α≥0.1 the reversible zone is in Λ≥101.7 and the totally irreversible zone is in Λ≥10-1.7, where Λ =k°/ [DO1-αDRα(nF/RT)v]1/2.
Page	57 - 63
Full Text	PDF

How to access to the WOL for The Bulletin of the Korean Chemical Society ?

The Bulletin of the Korean Chemical Society will be co-published with Wiley-VCH from 2015 towards. The online version of the Journal will thus be available on Wiley Online Library, Wiley(-VCH)'s global online platform.

KCS members can get a free online access to the Bulletin of the Korean Chemical Society in WOL.

Free Access to WOL