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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 14, Number 5
BKCSDE 14(5)
May 20, 1993 

Carbonylation of (Dichloromethyl)benzene Catalyzed by Cobalt Carbonyl and Iron Carbonyl under Phase Transfer Catalysis
Sang Chul Shim*, Chil Hoon Doh, Dong Yub Lee, Jae Goo Shim, Young Zoo Youn, Woo Hyun Park, Li Hong Jiang, Ju Hee kim
Treatment of (dichloromethyl)benzenes with CO (1 atm) in the presence of catalytic amount of Co2(CO)8, Fe(CO)5, and BTEAC under two phase systems with NaOH(aq) and PhCH3 containing small amount of alcohol for 20 hours at 80℃ gives phenylacetic acids in moderate yields.
618 - 620
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