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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 14, Number 1
BKCSDE 14(1)
January 20, 1993 

 
Title
A New Chiral Synthetic Route to (+)-Isocarbacyclin
Author
Hokoon Park*, Yong Sup Lee, Sang Chul Shim
Keywords
Abstract
A synthetic route to (+)-isocarbacyclin starting from (-)-tricyclo[3.3.0.02,8]octan-3-one 6 is described. The key intermediate 4 has been synthesized from 6 by a sequential introduction of methoxycarbonyl group at C-12 and the oxygen functionality at C-9α (PG numbering) for the construction of α-and ω-side chain, and then converted to isocarbacyclin methyl ester 2.
Page
86 - 91
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