Current time in Korea 19:29 Sep 19 (Sat) Year 2020 KCS KCS Publications
KCS Publications
My Journal  Log In  Register
HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 13, Number 5
BKCSDE 13(5)
May 20, 1992 

 
Title
Synthesis of Tetradecker Sandwich Complex with 1,4-Dialkyl-1,4-dibora-2,5-cyclohexadiene
Author
Jae-Kook Uhm*, Walter Siebert
Keywords
Abstract
A tetradecker sandwich compiex (7a) was synthesized in low yield by the reaction of a tripledecker, bis(η5-cyclopentadienyl)-μ-(η 6-1,2,3,4-tetramethyl 1,4-dibora-2,5-cyclohexadiene) dinickel (5a) with potassium and FeCl2·2THF. The reaction of another tripledecker, bis(η5-cyclopentadienyl)-μ-(η 6-2,3-diethyl-1,4-dimethyl-1,4-dibora-2,5-cyclohex adiene) dicobalt (4a) with potassium and FeCl2· 2THF at room temperature produced a doubledecker complex (2b) via the decomposition of the dark green crystal.
Page
528 - 530
Full Text
PDF