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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 13, Number 1
BKCSDE 13(1)
January 20, 1992 

 
Title
Deoxygenation of β-Aryl-α,β-Epoxy Silanes to Vinylsilanes by Magnesium-Magnesium Halide
Author
Kyung-Tae Kang*, Chun Yi Park, Joung Sook Kim
Keywords
Abstract
The reactions of β-aryl-α,β-epoxy silanes with magnesium bromide or magnesium iodide in the presence of excess magnesium in ether at room temperature afforded vinylsilanes in 18-100% yields. E-Vinylsilanes were predominant over Z-isomers (> 80%) regardless of the stereochemistry of α,β-epoxy silanes.
Page
48 - 53
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