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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 12, Number 4
BKCSDE 12(4)
April 20, 1991

Title	Direct Synthesis of Trisilaalkanes
Author	Il Nam Jung*, Gyu-Hwan Lee, Seung-Ho Yeon, Mi-Yeon Suk
Keywords
Abstract	A series of trisilaalkanes has been prepared in high yields by the direct reaction of α -chloromethylsilanes with metallic silicon in the presence of copper catalyst using the stirred reactor equipped with a spiral band agitator at the carefully controlled temperature between 280℃ and 340℃. Disilaalkane compounds were obtained as the minor products. Cadmium was found to be a good promotor for the reactions, while zinc was an inhibitor.
Page	445 - 449
Full Text	PDF

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