KCS Publications

HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 12, Number 3
BKCSDE 12(3)
March 20, 1991

Title	Reaction and Coordination Chemistry of Ferrocenylaminophosphines with Iron Carbonyls
Author	Tae-Jeong Kim*, Soon-Chul Kwon, Yong-Hoon Kim, Dong-Ho Lee
Keywords
Abstract	The reaction and coordination chemistry of chiral ferrocenylaminophosphines such as 2-(diphenylphosphino)-1-(N,N-dimethylaminoethyl) ferrocene (PPFA), and 1',2-bis(diphenylphosphino)-l-(N,N-dimethylaminoe thyl) ferrocene (BPPFA), with various iron carbonyls have been investigated. PPFA reacted with iron carbonyls, Fe(CO)5, Fe2(CO)9, or Fe3(CO)12 to give an iron complex of the type (η 1-PPFA-P)Fe(CO)4 (1) as a single product regardless the choice of the iron carbonyls. The bisphosphine ligand BPPFA afforded two products (η1-BPPFA-P)Fe(CO)4 (2) and (μ,η 1-BPPFA-P,P)Fe2(CO)8 (3) in which BPPFA acts as a monodentate and a bridging ligand, respectively. In all cases coordination to the -Fe(CO)4 moiety is made through the phosphine rather than the amino group and, in the case of 2, the coordination is made through the phosphine substituted at the C5H4 ring to reduce the steric congestion.
Page	332 - 334
Full Text	PDF

How to access to the WOL for The Bulletin of the Korean Chemical Society ?

The Bulletin of the Korean Chemical Society will be co-published with Wiley-VCH from 2015 towards. The online version of the Journal will thus be available on Wiley Online Library, Wiley(-VCH)'s global online platform.

KCS members can get a free online access to the Bulletin of the Korean Chemical Society in WOL.

Free Access to WOL