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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 11, Number 6
BKCSDE 11(6)
June 20, 1990 

Ehanced Electrogenerated Chemilumienscence of Tris (2,2'-bipyridyl) Ruthenium (Ⅱ)-S2O82- System by Sodium Dodecyl Sulfate
Sung Chul Kang, Sooil Oh, Kang-Jin Kim*
The electrochemical reduction and electrogenerated chemiluminescence (ECL) of Ru(bpy)32+-S2O82- in CH3CN-H2O solution were studied in the presence of sodium dodecyl sulfate (SDS) as an anionic surfactant. SDS enhanced the ECL and the fluorescence intensities and lengthened the duration of ECL due to the solubilization of reactants and possibly to the stabilization of ECL intermediates in the SDS micellar environment.
505 - 508
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