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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 11, Number 5
BKCSDE 11(5)
May 20, 1990 

 
Title
Carbonylation of Benzal Chlorides to Alkyl Phenylacetates using Fe(CO)5
Author
Sang Chul Shim*, Chil Hoon Doh, Sung Yub Lee, Chan Sik Cho
Keywords
Abstract
Various substituted benzal chlorides are converted into alkyl phenylacetates (ArCH2COOR) under CO atmosphere on reaction with a catalytic amount of Fe(CO)5, a base, and an alcohol. The optimum conditions are found as atmospheric pressure of CO, 40℃, potassium hydroxide as base, and medium of alcohol.
Page
420 - 422
Full Text
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