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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 11, Number 3
BKCSDE 11(3)
March 20, 1990 

Kinetic Studies on Dimer (CrMn(CO)10-) Disruptions
Yong Kwang Park, In Sup Han, Tae Sung Huh*
A kinetic study of the heterobimetallic dimer disruption of PPN + aCrMn(CO)10- by ligand L(L = CO, PR3) is described. The rate was determined in several aprotic solvents. The results indicated that the reaction of PPN + CrMn(CO)10- with PR3 is of first order with respect to [PPN + CrMn(CO)10-] and the heterolytic Cr-Mn bond dissociation energy is approximately 27 kcal/mol.
221 - 224
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