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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 10, Number 3
BKCSDE 10(3)
March 20, 1989 

 
Title
A Kinetic Study of the Chemiluminescent Reactions of Bis(2,4-dinitrophenyl)Oxalate, Hydrogen Peroxide and Fluorescent Polycyclic Aromatic Hydrocarbons
Author
Hyung Seon Shin, Sung Chul Kang, Kang-Jin Kim*
Keywords
Abstract
A kinetic study on the chemiluminescence resulting from the reaction between bis(2,4-dinitrophenyl) oxalate(DNPO) and hydrogen peroxide in the presence of fluorescent polycyclic aromatic hydrocarbons in a viscous phthalate medium has been conducted. The resultant data confirm that the reaction between DNPO and H2O2 is the rate determining step. Higher rate constants are obtained with DNPO than those with bis(2,4,6-trichlorophenyl) oxalate (TCPO).
Page
251 - 254
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