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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 10, Number 2
BKCSDE 10(2)
February 20, 1989 

Kinetic Studies of Reactions of Transition Metal Carbonyl Anion with Allyl Halides
Yong Kwang Park*, In Sup Han, Tae Sung Huh, Marcetta York Darensbourg
The reaction of CpMo(CO)3-M+(M+, Li+, Na+, K+, PPN+a) with allyl halide was performed and the details of its counterion effects and solvent effect was investigated under the pseudo-first order conditions. The kinetic data from this reaction were compared with those from the reaction of the same anion with benzyl halides in terms of their inverse counterion effects.
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