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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 9, Number 6
June 20, 1988 

Cross Interaction Constants As a Measure of the Transition State Structure (Part Ⅵ). Nucleophilic Substitution Reactions of Benzyl Chlorides with Anilines and Benzylamines
Ikchoon Lee*, Chul Huh, Han Joong Koh, Hai Whang Lee
Results of kinetic studies on the reactions of benzyl chlorides with anilines and benzylamines are reported. Analyses of the cross interaction constants relevant to the degree of bond formation, ρXY and λXY, are carried out. The magnitudes of the two parameters indicated that the degree of bond formation in the transition state is the typical of that expected for an SN2 reaction, but the reactions with benzylamines appear to have a slightly less degree of bond formation compared with the reactions with anilines.
376 - 378
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