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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 9, Number 3
March 20, 1988 

A Gas Phaes Kinetic Study of the Energy Transfer by using the High Power CO2 Laser. (Ⅱ). Decomposition of BrCH2CH2CH2CH2Cl
Yongsik Lee, Yangsik Kim, Sae Chae Jeoung, Kwang Yul Choo*
Infrared multiphoton decompositions (IRMPD) of BrCH2CH2CH2CH2Cl were studied by using the pulsed CO2laser. At 0.3 J laser energy the experimentally observed product ratios could be reasonably explained by the RRKM calculation with initial excitation energy of ca. 80 Kcal/mol. The pressure dependence of product yields led us to conclude that the collisional deactivation by the inert gas decreased the yield of low energy dissociatione channel more significantly.
161 - 164
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