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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 9, Number 1
BKCSDE 9(1)
January 20, 1988 

 
Title
Synthesis of Diaryl α-Diketones via Palladium Catalyzed Double Carbonylative Homo Coupling of Aryl Iodides with Carbon Monoxide
Author
Jin Il Kim*, Nam Jung Kim, Cheol Mo Ryu
Keywords
Abstract
Symmetrical diaryl α-diketones were synthesized in moderately good yields through the palladium catalyzed reaction of aryl iodides with carbon monoxide. The reaction was tolerant of a wide variety of fuctionalities(OCH3, CH3, NO2, OH, COOH) on the aryl iodide. On the other hand, the similar reaction of aryl bromides or chlorides with carbon monoxide did not proceed.
Page
30 - 32
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