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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 9, Number 1
BKCSDE 9(1)
January 20, 1988

Title	The Nature of the Intrinsic Barrier in Methyl Transfer Reactions
Author	Ikchoon Lee*, Chang Hyun Song
Keywords
Abstract	The intrinsic barrier in the methyl transfer reaction X- + CH3X ↔ XCH3 + X- has been shown to vary quadratically with the C-X distance d; linear dependence of the intrinsic barrier on the deformation energies or methyl cation affinities of the substrate, CH3X, should therefore hold only approximately in a narrow range of structural variations in X.
Page	10 - 12
Full Text	PDF

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